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The mole and Avogadro's constant - OCR GatewayMoles and masses - Higher

What is the mole and Avogadro's constant? The mole is the unit for amount of substance. The number of particles in a substance can be found using the Avogadro constant. The mass of product depends upon the mass of limiting reactant.

Part of Chemistry (Single Science)Chemical reactions

Moles and masses - Higher

Molar mass

The molar mass of a substance is the mass of one of that substance. It is equal to:

  • the or Ar in grams for and
  • the or Mr in grams for and

The table shows some examples.

SubstanceFormulaAr or MrMolar mass (g/mol)
NeonNeAr = 20.220.2
MagnesiumMgAr = 24.324.3
OxygenO2Mr = 2 脳 16.0 = 32.032.0
Calcium carbonateCaCO3Mr = 40.1 + 12.0 + (3 脳 16.0) = 100.1100.1
SubstanceNeon
FormulaNe
Ar or MrAr = 20.2
Molar mass (g/mol)20.2
SubstanceMagnesium
FormulaMg
Ar or MrAr = 24.3
Molar mass (g/mol)24.3
SubstanceOxygen
FormulaO2
Ar or MrMr = 2 脳 16.0 = 32.0
Molar mass (g/mol)32.0
SubstanceCalcium carbonate
FormulaCaCO3
Ar or MrMr = 40.1 + 12.0 + (3 脳 16.0) = 100.1
Molar mass (g/mol)100.1

Masses from moles

The of a substance in grams can be calculated from its amount in moles and its molar mass:

mass (g) = molar mass (g/mol) 脳 amount (mol)

Example

Calculate the mass of 0.25 mol of carbon dioxide molecules, CO2. (Relative atomic masses: C = 12.0, O = 16.0)

relative formula mass, Mr = 12.0 + (2 脳 16.0) = 44.0

molar mass = 44.0 g/mol

= 11.0 g

The calculation is the same if a substance is a metal or exists as separate atoms, but its Ar is used to work out the molar mass instead of an Mr.

Question

Calculate the mass of 0.10 mol of iron. (Relative atomic mass: Fe = 55.8)

Moles from masses

The amount of a substance in moles can be calculated from its mass in grams and its molar mass:

\(amount\ (mol)\ = \frac{mass (g)}{molar\ mass\ (g/mol)}\)

Example

Calculate the amount of carbon atoms in 6.0 g of carbon. (Relative atomic mass: C = 12.0)

molar mass = 12.0 g/mol

\(amount\ =\ \frac{6.0}{12.0}\)

= 0.50 mol

Question

Calculate the amount of water molecules in 22.5 g of water, H2O. (Relative atomic masses: H = 1.0, O = 16.0)