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Exothermic and endothermic reactions - AQAReaction profiles

Exothermic reactions transfer energy to the surroundings and the temperature of the surroundings increases. Endothermic reactions take in energy and the temperature of the surroundings decreases.

Part of Combined ScienceEnergy changes

Reaction profiles

An shows whether a reaction is or . It shows the energy in the and , and the difference in energy between them.

Exothermic reaction

The energy level decreases in an exothermic reaction. This is because energy is given out to the surroundings.

Graph of energy against progress of reaction. Horizontal line represents reactants energy. Drops vertically as energy released. Horizontal line at a lower level represents products' energy.
Figure caption,
A downwards arrow shows that energy is given out

Endothermic reaction

The energy level increases in an endothermic reaction. This is because energy is taken in from the surroundings.

Graph of energy against progress of reaction. A horizontal line represents the reactants' energy. It rises vertically as energy is absorbed. A horizontal line at a higher level then represents the products' energy.
Figure caption,
An upwards arrow shows that energy is taken in

It is usually more helpful to describe how the energy of the chemicals changes during the reaction, so a is more useful than an energy level diagram.

A reaction profile includes the , which is the minimum energy needed by particles when they collide for a reaction to occur. The activation energy is shown as a 'hump' in the line, which:

  • starts at the energy of the reactants
  • is equal to the difference in energy between the top of the 'hump' and the reactant

The overall change in energy in a reaction is the difference between the energy of the reactants and products.

Exothermic reactions

The diagram shows a reaction profile for an exothermic reaction.

A reaction profile for an exothermic reaction showing the overall change in energy.
Figure caption,
A reaction profile for an exothermic reaction

Question

Describe how you can tell from a reaction profile that a reaction is exothermic.

Endothermic reactions

The diagram shows a reaction profile for an endothermic reaction.

A reaction profile for an endothermic reaction.
Figure caption,
A reaction profile for an endothermic reaction

Question

Describe how you can tell from a reaction profile that a reaction is endothermic.