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Alcohols and carboxylic acids - EdexcelEthanol

Alcohols contain the 鈥揙H functional group. Ethanol is made from sugars by fermentation, and concentrated using fractional distillation. Carboxylic acids contain the 鈥揅OOH functional group.

Part of Chemistry (Single Science)Separate chemistry 2

Ethanol

Ethanol is the found in beer, wine and other alcoholic drinks. It is also used as a for vehicles, either on its own or mixed with petrol. Ethanol can be produced by and concentrated using .

Fermentation

Fermentation is an process (it happens in the absence of oxygen):

Glucose 鈫 ethanol + carbon dioxide

, a type of single-celled , provides the needed for fermentation. If the yeast become too cold, fermentation happens very slowly, or may not happen at all. If the yeast cells become too hot, their enzymes become and fermentation stops.

The typical conditions needed for fermentation include:

  • sugars in water, and mixed with yeast
  • an air lock to allow carbon dioxide out, while stopping air getting in
  • warm , 25-35掳C

The yeast dies when the ethanol reaches about 15%. Fermentation is a slow reaction and takes several days or weeks to finish. If air is present, the oxygen causes the ethanol to oxidise to ethanoic acid, so the drink tastes of vinegar.

Two test tubes connected by tube. Left tube contains yeast in sugar solution, vegetable oil on top.  Right tube contains limewater. Bubbles are coming from bottom of connecting tube within limewater.
Figure caption,
Apparatus used to investigate fermentation in the lab

Question

Describe and explain what happens to the limewater during the experiment shown above.

Fractional distillation

The fermentation mixture contains yeast cells and substances. These are separated from the impure ethanol solution by . Fractional distillation is then used to produce a concentrated solution of ethanol from the . This works because ethanol and water have different . When the mixture is heated, ethanol more readily.

Image gallerySkip image gallerySlide 1 of 3, In the first stage of ethanol distillation, water and ethanol solution is heated., Distillation process to separate ethanol from water 1. Water and ethanol solution is heated

It is safer to use an electric heater instead of a Bunsen burner. This is because ethanol liquid and vapour are highly , and could be set on fire by accident.