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Atomic structure - AQAIsotopes

Atoms consist of a nucleus containing protons and neutrons, surrounded by electrons in shells. The number of subatomic particles in an atom can be calculated from the atom's atomic number and mass number.

Part of Chemistry (Single Science)Atomic structure and the periodic table

Isotopes

of the same element must have the same number of , but they can have different numbers of . Atoms of the same element with different numbers of neutrons are called . Isotopes of an element have:

  • the same
  • different

Learn more on isotopes in this podcast.

Three isotopes of hydrogen

All hydrogen atoms contain one proton (and one ), but they can contain different numbers of neutrons. Hydrogen-1 is the most abundant (most common) isotope of hydrogen.

IsotopeSymbolProtonsElectronsNeutrons
Hydrogen-1\(_{1}^{1}\textrm{H}\)111 - 1 = 0
Hydrogen-2\(_{1}^{2}\textrm{H}\)112 - 1 = 1
Hydrogen-3\(_{1}^{3}\textrm{H}\)113 - 1 = 2
IsotopeHydrogen-1
Symbol\(_{1}^{1}\textrm{H}\)
Protons1
Electrons1
Neutrons1 - 1 = 0
IsotopeHydrogen-2
Symbol\(_{1}^{2}\textrm{H}\)
Protons1
Electrons1
Neutrons2 - 1 = 1
IsotopeHydrogen-3
Symbol\(_{1}^{3}\textrm{H}\)
Protons1
Electrons1
Neutrons3 - 1 = 2

An isotope is named after the element and the mass number of its atoms. For example, carbon-12 is an isotope of carbon with a mass number of 12.

All three isotopes of hydrogen have identical . This is because the number of electrons determines chemical properties, and all three isotopes have one electron in their atoms.

Relative atomic mass

can be found in the periodic table. They have the symbol Ar.

Take care not to confuse mass numbers and relative atomic masses:

  • mass numbers are always whole numbers (protons or neutrons cannot be split into parts)
  • relative atomic masses are often rounded to the nearest whole number, but are actually not whole numbers

For example, the relative atomic mass of chlorine is 35.5 rather than a whole number. This is because chlorine contains two different isotopes, chlorine-35 and chlorine-37.