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Bonding, structure and properties of materials - OCR 21st CenturyComparing giant structures

Different materials can be made from atoms of the same element. The properties of the material depend upon the bonding between the atoms and structure of the substance.

Part of Chemistry (Single Science)Material choices

Comparing giant structures

Giant covalent structures

leads to the formation of . These can be:

  • simple molecules, which contain a set number of atoms joined by covalent bonds
  • giant substances, which contain many atoms joined by covalent bonds

An example - silica

Silica is the main found in sand. It is an example of a giant covalent substance. It contains many silicon and oxygen atoms. These are joined together by covalent bonds in a regular arrangement, forming a .

A ball and stick model of silica
Figure caption,
Silica has a giant covalent structure containing silicon atoms (grey) and oxygen atoms (red)

Giant covalent substances are solids at room temperature and have very high and . Covalent bonds are strong, so a lot of is needed to break up these large structures during melting and boiling.

Giant covalent substances have no overall , so most cannot electricity. Graphite, a form of carbon which can conduct electricity, is an exception.

Giant ionic lattices

The structure of an is a giant ionic lattice.

Large numbers of oppositely charged are arranged in an alternating, regular three-dimensional structure. The electrostatic attraction between opposite charges is called an .

Ionic structure of sodium chloride forming a cubic lattice
Figure caption,
A giant ionic lattice structure

Ionic bonds are very strong so the melting point of an ionic compound is high.

Ionic compounds do not conduct electricity in the solid state because their ions are unable to move about. However, if an ionic compound is melted or dissolved, its ions become free to move about and it can conduct electricity.

Metallic structures

The structure of metals is based on a three-dimensional arrangement with layers of positive metal ions surrounded by a sea of negative . The electrostatic attraction between the positive metal ions and the negative sea of electrons is called metallic bonding.

Delocalised electrons moving freely among an array of tightly packed metal atoms.
Figure caption,
A giant metallic structure

Metallic bonds are very strong so in general metals have high melting points and are strong and hard.

The layers of metal ions are able to slide across each other. This makes metals and .

The electrons are free to move so metals are good conductors of electricity.