Substances with many covalent bonds
covalent bondA bond between atoms formed when atoms share electrons to achieve a full outer shell of electrons. leads to the formation of moleculeA collection of two or more atoms held together by chemical bonds.. These can be:
- simple molecules, which contain a set number of atomThe smallest part of an element that can exist. joined by covalent bonds
- giant covalentA covalent substance is a molecule containing one or more covalent bonds (shared pairs of electrons). substances, which contain many atoms joined by covalent bonds
Learn more on properties of giant covalent compounds in this podcast.
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An example - silica
Silica is the main compoundA substance formed by the chemical union of two or more elements. found in sand. It is an example of a giant covalent substance. It contains many silicon and oxygen atoms. These are joined together by covalent bonds in a regular arrangement, forming a giant covalent network Giant regular arrangement of atoms, with a repeating pattern, held together by covalent bonds. or latticeA regular grid-like arrangement of atoms in a material. structure. There is no set number of atoms joined together in this type of structure, so these covalent lattices are not classed as molecules. However, the atoms in the compound will be present in the ratio indicated by the chemical formulaA combination of symbols that indicates the chemical composition of a substance..
High melting points and boiling points
Giant covalent substances are solids at room temperature and have very high melting pointThe temperature at which a solid changes into a liquid as it is heated. and boiling pointThe temperature at which a substance rapidly changes from a liquid to a gas.. Covalent bonds are strong, so a lot of energyThe capacity of a system to do work or the quantity required for mechanical work to take place. Measured in joules (J). For example, a man transfers 100 J of energy when moving a wheelbarrow. is needed to break up these large structures during melting and boiling.
Conduction of electricity
Giant covalent substances have no overall chargeProperty of matter that causes a force when near another charge. Charge comes in two forms, positive and negative. For example, a negative charge causes a repulsive force on a neighbouring negative charge., so most cannot conductTo allow electricity, heat or other energy forms to pass through. electricity. Graphite, a form of carbon, which can conduct electricity, is an exception.
Insoluble in water
A substance can dissolveWhen a substance breaks up and mixes completely with a solvent to produce a solution. in water if it forms strong enough attractions with water molecules. Giant covalent substances cannot form these strong attractions with water, so they are insolubleUnable to dissolve in a particular solvent. For example, sand is insoluble in water..
More guides on this topic
- Equations and formulae - Edexcel
- Hazards and risks - Edexcel
- Atomic structure - Edexcel
- The periodic table - Edexcel
- Ionic compounds - Edexcel
- Simple molecular substances - Edexcel
- Metals and non-metals - Edexcel
- Chemistry calculations - Edexcel
- Mole calculations (higher) - Edexcel
- Sample exam questions - key concepts in chemistry - Edexcel