Reactivity of halogens
The non-metal elementA substance made of one type of atom only. in Group 7 鈥 known as the halogenAn element placed in Group 7 of the periodic table, which starts with fluorine and ends with astatine. The name 鈥榟alogen鈥 means 鈥榮alt-producing鈥 because halogens produce a range of salts when they react with metals. 鈥 get less reactive as you go down the group. This is the opposite trend to that seen in the alkali metals in Group 1The first vertical column of elements in the periodic table, starting with lithium and ending with francium. Also called the alkali metals. of the periodic tableA tabular representation of all known elements in order based on atomic number, eg all the noble gases are found on the right of the periodic table..
Fluorine is the most reactive element of all in Group 7.
You can see the trend in reactivity if you react the halogens with iron wool.
Halogen | Reaction with iron wool |
Fluorine | Reacts with almost anything instantly. Very few scientists handle fluorine because it is so dangerous. Produces iron(III) fluoride. |
Chlorine | Reacts with heated iron wool very quickly, although not as quickly as fluorine does. Produces iron(III) chloride. |
Bromine | Has to be warmed and the iron wool heated. The reaction is faster than that of iodine but slower than that of chlorine. Produces iron(III) bromide. |
Iodine | Has to be heated strongly and so does the iron wool. The reaction is slow. Produces iron(III) iodide. |
Halogen | Fluorine |
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Reaction with iron wool | Reacts with almost anything instantly. Very few scientists handle fluorine because it is so dangerous. Produces iron(III) fluoride. |
Halogen | Chlorine |
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Reaction with iron wool | Reacts with heated iron wool very quickly, although not as quickly as fluorine does. Produces iron(III) chloride. |
Halogen | Bromine |
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Reaction with iron wool | Has to be warmed and the iron wool heated. The reaction is faster than that of iodine but slower than that of chlorine. Produces iron(III) bromide. |
Halogen | Iodine |
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Reaction with iron wool | Has to be heated strongly and so does the iron wool. The reaction is slow. Produces iron(III) iodide. |
Iron + chlorine 鈫 iron(III) chloride
2Fe + 3Cl2 鈫 2FeCl3
Iron + bromine 鈫 iron(III) bromide
2Fe + 3Br2 鈫 2FeBr3
Iron + iodine 鈫 iron(III) iodide
2Fe + 3I2 鈫 2FeI3