Summary of bonding types
There are four kinds of bonding types to be aware of. These are ionic bondingIonic bonding forms between two atoms when an electron is transferred from one atom to the other, forming a positive-negative ion pair., simple covalent molecular, giant covalent network and metallic.
The table below summarises them, identifying typical properties of each. Simple covalent molecular is listed as 'simple' and giant covalent network is listed as 'giant'.
Ionic | Simple | Giant | Metallic |
Metals and non-metals | Non-metals | Non-metals | Metals |
Loss and gain of electrons by atoms | Share pairs of electrons between atoms | Share pairs of electrons between atoms | Outer electrons free to move |
+ and - ions formed attract each other | Small groups of atoms held together | Billions of atoms are held together | Billions of positive metal ions |
Ionic lattice structure | A molecular structure | Giant covalent lattice structure | Giant metallic lattice structure |
Ionic | Metals and non-metals |
---|---|
Simple | Non-metals |
Giant | Non-metals |
Metallic | Metals |
Ionic | Loss and gain of electrons by atoms |
---|---|
Simple | Share pairs of electrons between atoms |
Giant | Share pairs of electrons between atoms |
Metallic | Outer electrons free to move |
Ionic | + and - ions formed attract each other |
---|---|
Simple | Small groups of atoms held together |
Giant | Billions of atoms are held together |
Metallic | Billions of positive metal ions |
Ionic | Ionic lattice structure |
---|---|
Simple | A molecular structure |
Giant | Giant covalent lattice structure |
Metallic | Giant metallic lattice structure |
Comparing models
The different bonding modelA description of how a chemical bond is formed and/or the structure produced by the atoms. Bonding models can often be used to explain the properties of a substance. that are used to represent the bonding and structure of substances have certain features and limitations. For example, the model of the metallic latticeA regular grid-like arrangement of atoms in a material. on the previous page does not show more than one layer of metal ionElectrically charged particle, formed when an atom or molecule gains or loses electrons., or that the delocalisedElectrons that are not associated with a particular atom, eg in a metal, outer electrons can be free to move through the solid. electronSubatomic particle, with a negative charge and a negligible mass relative to protons and neutrons. are in constant motion.
Models for ionic compounds
ionic compoundAn ionic compound occurs when a negative ion (an atom that has gained an electron) joins with a positive ion (an atom that has lost an electron). form a regular lattice structure in which oppositely charged ions are strongly attracted to each other. Sodium chloride is an ionic compound. The table shows some limitations of different models for sodium chloride.
Models for simple molecular substances
The atomThe smallest part of an element that can exist. in a simple molecularRefers to a substance made up of molecules, so it contains small groups of atoms, of a set size, held together by covalent bonds. substance are joined together by strong covalent bondA bond between atoms formed when atoms share electrons to achieve a full outer shell of electrons.. moleculeA collection of two or more atoms held together by chemical bonds. are attracted to each other by weak intermolecular forcesWeak attractive forces between molecules. When a simple molecular substance melts or boils, it is the intermolecular forces that are broken (not the covalent bonds in each molecule).. Water is a simple molecular substance. The table shows some limitations of different models of water.
More guides on this topic
- Equations and formulae - Edexcel
- Hazards and risks - Edexcel
- Atomic structure - Edexcel
- The periodic table - Edexcel
- Ionic compounds - Edexcel
- Simple molecular substances - Edexcel
- Giant covalent substances - Edexcel
- Chemistry calculations - Edexcel
- Mole calculations (higher) - Edexcel
- Sample exam questions - key concepts in chemistry - Edexcel