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Calculations in chemistry - AQA SynergyConcentration of solutions

Relative formula masses can be calculated and used in conservation of mass calculations. Calculations can be carried out to find out concentrations of solutions.

Part of Combined ScienceBuilding blocks for understanding

Concentration of solutions

A forms when a in a . The of a solution is a measure of how 'crowded' the solute particles are. The more concentrated the solution, the more particles it contains in a given .

Calculating concentration

The concentration of a solution can be calculated using:

  • the of dissolved solute in grams, g
  • the volume of solution (or solvent) in cubic decimetres, dm3

The units for concentration can also be shown as g dm-3, but this means the same as g/dm3.

Worked example

8 g of sodium hydroxide is dissolved in 2 dm3 of water. Calculate the concentration of the sodium hydroxide solution formed.

concentration = \(\frac{\textup{mass~of~solute~in~g}}{\textup{volume~in~dm}^3}\)

concentration = \(\frac{\textup{8~g}}{\textup{2~dm}^3}\)

concentration = 4 g/dm3

Volume units

Apparatus used to measure volumes is usually marked in cm3 or ml. Although these are different units, they describe the same volume. For example, 250 ml = 250 cm3.

Volumes used in concentration calculations must be in dm3, not in cm3 or ml. It is useful to know that 1 dm3 = 1000 cm3. This means:

  • divide by 1000 to convert from cm3 to dm3
  • multiply by 1000 to convert from dm3 to cm3

For example, 250 cm3 is 0.25 dm3 (250 梅 1000). It is often easiest to convert from cm3 to dm3 before continuing with a concentration calculation.

Question

100 cm3 of dilute hydrochloric acid contains 0.5 g of dissolved hydrogen chloride. Calculate the concentration of the acid in g/dm3.

Calculating the mass of solute

Rearranging the equation for concentration allows the mass of solute to be calculated:

mass of solute in g = concentration in g/dm3 脳 volume in dm3

Worked example

A solution of sodium chloride has a concentration of 10 g/dm3. What mass of sodium chloride is dissolved in 2 dm3 of the solution?

mass of solute in g = concentration in g/dm3 脳 volume in dm3

= 10 g/dm3 脳 2 dm3

= 20 g

Higher tier

The concentration of a solution can be changed:

  • concentration can be increased by dissolving more solute in a given volume of solution - this increases the mass of the solute
  • concentration can be increased by allowing some of the solvent to evaporate - this decreases the volume of the solution