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Finding the composition of unknown samplesInstrumental methods of analysis

Quantitative analysis is used by chemists to make measurements and calculations. Alkalis neutralise acids to make salts and water. Their concentration can be analysed using titrations.

Part of Chemistry (Single Science)Chemical analysis

Instrumental methods of analysis

Instrumental methods of analysis rely on machines. There are several different types of instrumental analysis. Some are suitable for detecting and identifying , while others are better suited to . Data can be automatically recorded.

Compared to simple laboratory tests, instrumental methods of analysis may give improved:

  • speed (they are quick)
  • accuracy (they reliably identify elements and compounds)
  • sensitivity (they can detect very small amounts of a substance in a small amount of sample)

The disadvantage is that analytical instruments are very expensive so tests using laboratory glassware are cheaper and more readily available.

Identifying metal ions

A flame photometer can be used to identify metal ions. The coloured light from a sample can be split to produce an . The different lines in an emission spectrum look like a coloured barcode. Each produces a unique emission spectrum.

An emission spectrum for mercury.
Figure caption,
An emission spectrum for mercury

The metal present in a sample is identified by comparing its with reference spectra. These are emission spectra from known metal ions. If two spectra match, they must be from the same metal ion.

Emission spectroscopy

An emission spectrometer analyses the spectrum from a hot sample. It can record the exact of the light that is emitted by the sample.

It can then match the pattern and wavelengths to reference data for known elements.

Emission spectroscopy is used to analyse substances in the steel industry and also to identify elements in stars.