Alkanes
The alkaneSaturated hydrocarbon. A compound of hydrogen and carbon only, with no C=C bonds. form a homologous seriesA 'family' of organic compounds that have the same functional group and similar chemical properties. . Like all homologous series, the alkanes:
- have the same general formulaAn algebraic formula that sets out a rule or trend which is followed by all members of a homologous series. For example, all non-cyclic alkanes have the general formula CnH2n+2.
- show a gradual variation in physical propertiesThe characteristics of something. In chemistry, chemical properties include the reactions a substance can take part in. Physical properties include colour and boiling point., such as their boiling pointThe temperature at which a substance rapidly changes from a liquid to a gas.
- have similar chemical properties
General formula
The general formula for the alkanes is CnH2n+2, where n is the number of carbon atoms in the molecule.
Worked example
Decane is an alkane. Its moleculeA collection of two or more atoms held together by chemical bonds. contain 10 carbon atomThe smallest part of an element that can exist.. Predict the molecular formula of decane and explain your answer.
The formula will be C10H22. This is because n = 10. So, 2n + 2 = (2 脳 10) + 2 = 20 + 2 = 22.
Question
Hexane is an alkane. Its molecules contain six carbon atoms. Predict the molecular formula of hexane.
The formula will be C6H14.
Structures
The table shows four alkanes, their molecular formulae and their structures.
The ball and stick models on the right show that the covalent bondA bond between atoms formed when atoms share electrons to achieve a full outer shell of electrons. are not really at angles of 90掳, as shown in the structures.
The alkanes are saturatedA saturated hydrocarbon contains no carbon-to-carbon double bonds, only single bonds. hydrocarbonA compound that contains hydrogen and carbon only.:
- Hydrocarbons, because they are compounds containing hydrogen and carbon only.
- Saturated, because they only contain single bonds. Each atom has formed its maximum number of bonds.