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Redox, extraction of iron and transition metalsOxidation and reduction

Redox reactions are involved in the extraction of metals from their ores, eg extracting iron by reduction within the blast furnace. Transition metals have high melting points and densities, form coloured compounds and act as catalysts.

Part of Chemistry (Single Science)Metals and their extraction

Oxidation and reduction

Oxidation is the loss of from a substance. It is also the gain of oxygen by a substance. For example, magnesium is oxidised when it reacts with oxygen to form magnesium oxide:

magnesium + oxygen 鈫 magnesium oxide

2Mg + O2 鈫 2MgO

Reduction is the gain of electrons by a substance. It is also the loss of oxygen from a substance. For example, copper(II) oxide can be reduced to form copper when it reacts with hydrogen:

copper(II) oxide + hydrogen 鈫 copper + water

CuO + H2 鈫 Cu + H2O

Usually, oxidation and reduction take place at the same time in a reaction. We call this type of reaction a redox reaction (red 鈥 reduction, ox 鈥 oxidation).

Note that:

  • the oxidising agent is the chemical that causes oxidation by providing oxygen
  • the reducing agent causes the other chemical to be reduced by removing oxygen

Take a look at the following :

aluminium + iron(III) oxide 鈫 iron + aluminium oxide

2Al + Fe2O3 鈫 2Fe + Al2O3

Aluminium has been oxidised. This means that the iron(III) oxide is the oxidising agent. We can also see that the iron(III) oxide has been reduced. This means that the aluminium is the reducing agent.