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Making chemicals on an industrial scaleFertilisers

In industrial reactions, an acceptable yield in an acceptable time is needed. Catalysts increase the rate of the desired reaction, which helps to reduce the energy demand and cost of a process.

Part of Chemistry (Single Science)Making useful chemicals

Fertilisers

provide that are needed for healthy growth in plants. As plants grow, they absorb mineral ions from the water in the soil through their . Over time, the of these ions decreases, so farmers and gardeners add fertilisers to the soil.

Fertilisers are usually sold as solid powders or granules
Image caption,
Fertilisers are usually sold as solid powders or granules

Meeting world food demand

The world demand for food is so high that it is difficult to supply natural fertilisers in large enough quantities. They are difficult to transport and their mineral content is variable.

fertilisers can be manufactured and transported. The mineral content can be kept consistent.

Overuse of fertilisers

A major problem with the use of fertilisers occurs when rainwater washes them off the land into rivers and lakes. This causes an increase in the concentration of nitrate ions or phosphate ions in the water. grow faster because of this, and form an over the water surface. The bloom prevents sunlight reaching other water plants, which then die. Bacteria break down the dead plants. The bacteria respire and use up the oxygen in the water, so the lake may be left completely lifeless. This process is called .

Eutrophication and how it affects ecosystems.
Figure caption,
The stages of eutrophication

Nitrogen, phosphorus and potassium

Fertilisers may contain nitrogen, phosphorus and potassium to promote plant growth. Fertilisers that supply all three are often called NPK fertilisers, after the chemical symbols for these three elements.

Fertiliser compounds must be in water so they can be absorbed by the root hair cells:

  • ammonium ions, NH4+, and nitrate ions, NO3-, are sources of soluble nitrogen
  • phosphate ions, PO43-, are a source of soluble phosphorus
  • all common potassium compounds in water to produce potassium ions, K+

The table shows some examples of fertilisers, their and the essential elements they provide.

FertiliserFormulaEssential element(s)
Ammonium nitrateNH4NO3Nitrogen
Ammonium sulfate(NH4)2SO4Nitrogen
Ammonium phosphate(NH4)3PO4Nitrogen, phosphorus
Potassium nitrateKNO3Potassium, nitrogen
FertiliserAmmonium nitrate
FormulaNH4NO3
Essential element(s)Nitrogen
FertiliserAmmonium sulfate
Formula(NH4)2SO4
Essential element(s)Nitrogen
FertiliserAmmonium phosphate
Formula(NH4)3PO4
Essential element(s)Nitrogen, phosphorus
FertiliserPotassium nitrate
FormulaKNO3
Essential element(s)Potassium, nitrogen

Question

Urea, (NH2)2CO, is used as a fertiliser. Name the essential element it provides.