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Laboratory vs industrial manufacture of ammonium sulfate

Ammonium sulfate, (NH4)2SO4, is a used as a . It is a source of nitrogen, so it can be used as a 鈥榥itrogenous鈥 fertiliser.

Salts can be made in - reactions in the laboratory. These must be scaled up for industrial production and the process has to be adapted for larger quantities.

Making ammonium sulfate in the lab

Ammonium sulfate can be made in the lab using dilute ammonia solution and dilute sulfuric acid:

ammonia + sulfuric acid \(\rightarrow\) ammonium sulfate

2NH3(aq) + H2SO4(aq) \(\rightarrow\) (NH4)2SO4(aq)

Both are soluble, so must be used. The end-point of the titration indicates when the ammonia has been by the sulfuric acid. It is very important that there is no sulfuric acid is left in the mixture when the salt solution is .

Burette dripped acid into a known volume of alkali containing a few drops of indicator

The industrial production of ammonium sulfate

The industrial production of ammonium sulfate happens on a much larger scale than its production in the lab. A fertiliser factory often begins with the needed to make ammonia and sulfuric acid, rather than buying these two reactants from elsewhere. Several stages are needed.

A flow chart showing some of the stages in making ammonium sulfate
Figure caption,
A flow chart showing some of the stages in making ammonium sulfate

The lab preparation of ammonium sulfate is a 'batch' process. Only a small amount of is made slowly at any one time. The apparatus is then cleaned and made ready for another batch. The industrial production of ammonium sulfate is a 'continuous' process. The product is made quickly all the time, as long as raw materials are provided.

Use of by-products

Ammonium sulfate can be produced in industry by other methods which use the of other processes. Using by-products, or waste from other processes, as the helps to reduce use of raw materials and improves .