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The periodic table - EdexcelElectronic configurations

Mendeleev made an early periodic table. In the modern periodic table, elements are in order of atomic number in periods and groups. Electronic configurations model how electrons are arranged in atoms.

Part of Chemistry (Single Science)Key concepts in chemistry

Electronic configurations

An electronic configuration is the way in which are arranged in an .

Electrons in shells

Different shells can hold different maximum numbers of electrons. Electrons occupy shells starting with the innermost one. They begin to occupy the next shell when a shell becomes full.

For elements with atomic number 1 to 20:

Electron shellMax electrons
First2
Second8
Third8
Electron shellFirst
Max electrons2
Electron shellSecond
Max electrons8
Electron shellThird
Max electrons8

Predicting an electronic configuration

The electronic configuration of an atom can be predicted from its . For example, the atomic number of sodium is 11. Sodium atoms have 11 and so 11 electrons:

  • 2 electrons occupy the first shell
  • 8 electrons occupy the second shell
  • 1 electron occupies the third shell

This electronic configuration can be written as 2.8.1 (each dot separates one shell from the next). This electronic configuration can also be shown as a diagram. In these diagrams:

  • each shell is modelled as a circle
  • each electron is modelled as a dot or a cross
Structure of a sodium atom
Figure caption,
The electronic configuration of sodium as a diagram