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Limestone [GCSE Chemistry only]The limestone cycle

This topic covers the thermal stabilities of different metal carbonates, as well as specific reactions and uses of limestone (calcium carbonate) and the wider implications of its use.

Part of Chemistry (Single Science)Limestone

The limestone cycle

Calcium carbonate

Calcium carbonate, calcium oxide and calcium hydroxide are all made from limestone and have important applications so it is important to know how they are made.

Diagram show the set-up for heating calcium carbonate, to make calcium oxide and carbon dioxide.

Calcium carbonate is found naturally in . When limestone is heated strongly, the calcium carbonate it contains absorbs heat () and to form calcium oxide. This is indicated by an orange glow as the limestone is heated.

calcium carbonate → calcium oxide + carbon dioxide

CaCO3(s) → CaO(s) + CO2(g)

Calcium oxide (also known as quicklime) is a key ingredient in the making of cement and is also used to make certain types of plaster.

Calcium oxide

Calcium oxide reacts with a few drops of water to form calcium hydroxide, which is an . This is an reaction, indicated by the water turning to steam. The solid remains white but crumbles into a powder as the water is added.

calcium oxide + water → calcium hydroxide

CaO(s) + H2O(l) → Ca(OH)2(s)

Calcium hydroxide

Calcium hydroxide (also known as slaked lime) is used to excess acidity, for example, in lakes and soils affected by .

Calcium hydroxide dissolves in excess water to produce calcium hydroxide solution (limewater), which is used to test for carbon dioxide. The carbon dioxide reacts with the calcium hydroxide to form white calcium carbonate, which is insoluble and so turns the limewater ‘milky’.

calcium hydroxide + carbon dioxide → calcium carbonate + water

Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l)

Diagram showing how carbon dioxide reacts with calcium hydroxide to form white calcium carbonate, which is insoluble and so turns the limewater ‘milky’.

All of these reactions are linked together and form the limestone cycle.

Diagram of the limestone cycle.