大象传媒

Covalent bonding

A covalent bond forms when two non-metal share a pair of . The electrons involved are in the outer shells of the atoms. An atom that shares one or more of its electrons will complete its outer shell.

Covalent bonds are strong 鈥 a lot of energy is needed to break them. Substances with covalent bonds often form with low melting and boiling points, such as hydrogen and water. These substances have strong covalent bonds within the molecules (between the atoms), but weak intermolecular forces between the molecules. This means that only a small amount of heat energy is required to separate the molecules from each other.

Diagram showing the very weak forces of attraction between molecules, and the strong covalent bonds inside the molecules of ammonia.

The slideshow shows a covalent bond being formed between a hydrogen atom and a chlorine atom, to form hydrogen chloride.

Image gallerySkip image gallerySlide 1 of 2, A hydrogen atom with one electron and a chlorine atom with 17 atoms., 1. A hydrogen atom with one electron and a chlorine atom with 17 electrons

After bonding, the chlorine atom is now in contact with eight electrons in its outer shell, so it is . The hydrogen atom is now in contact with two electrons in its outer shell, so it is also stable.

Both are strongly attracted to the shared pair of electrons in the covalent bond, so covalent bonds are very strong and require a lot of energy to break.

How many bonds?

Atoms may form multiple covalent bonds 鈥 they share not only one pair of electrons, but two or more pairs. Atoms of different will form either one, two, three or four covalent bonds with other atoms.

There is a quick way to work out how many covalent bonds an element will form.

The table gives more detail on this rule.

ElementNumber of bonds
Group 4Carbon8 - 4 = 4
Group 5Nitrogen8 - 5 = 3
Group 6Oxygen8 - 6 = 2
Group 7Chlorine8 - 7 = 1
Group 4
ElementCarbon
Number of bonds8 - 4 = 4
Group 5
ElementNitrogen
Number of bonds8 - 5 = 3
Group 6
ElementOxygen
Number of bonds8 - 6 = 2
Group 7
ElementChlorine
Number of bonds8 - 7 = 1

Hydrogen forms one covalent bond. The noble gases in Group 0 do not form any.