Covalent bonding
A covalent bond forms when two non-metal atomAll elements are made of atoms. An atom consists of a nucleus containing protons and neutrons, surrounded by electrons. share a pair of electronSubatomic particle, with a negative charge and a negligible mass relative to protons and neutrons.. The electrons involved are in the outer shells of the atoms. An atom that shares one or more of its electrons will complete its outer shell.
Covalent bonds are strong 鈥 a lot of energy is needed to break them. Substances with covalent bonds often form moleculeA collection of two or more atoms held together by chemical bonds. with low melting and boiling points, such as hydrogen and water. These substances have strong covalent bonds within the molecules (between the atoms), but weak intermolecular forces between the molecules. This means that only a small amount of heat energy is required to separate the molecules from each other.
The slideshow shows a covalent bond being formed between a hydrogen atom and a chlorine atom, to form hydrogen chloride.
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After bonding, the chlorine atom is now in contact with eight electrons in its outer shell, so it is stableAtoms are stable if their outer shell contains its maximum number of electrons.. The hydrogen atom is now in contact with two electrons in its outer shell, so it is also stable.
Both nucleusThe central part of an atom. It contains protons and neutrons, and has most of the mass of the atom. The plural of nucleus is nuclei. are strongly attracted to the shared pair of electrons in the covalent bond, so covalent bonds are very strong and require a lot of energy to break.
How many bonds?
Atoms may form multiple covalent bonds 鈥 they share not only one pair of electrons, but two or more pairs. Atoms of different elementA substance made of one type of atom only. will form either one, two, three or four covalent bonds with other atoms.
There is a quick way to work out how many covalent bonds an element will form.
The table gives more detail on this rule.
Element | Number of bonds | |
Group 4 | Carbon | 8 - 4 = 4 |
Group 5 | Nitrogen | 8 - 5 = 3 |
Group 6 | Oxygen | 8 - 6 = 2 |
Group 7 | Chlorine | 8 - 7 = 1 |
Group 4 | |
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Element | Carbon |
Number of bonds | 8 - 4 = 4 |
Group 5 | |
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Element | Nitrogen |
Number of bonds | 8 - 5 = 3 |
Group 6 | |
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Element | Oxygen |
Number of bonds | 8 - 6 = 2 |
Group 7 | |
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Element | Chlorine |
Number of bonds | 8 - 7 = 1 |
Hydrogen forms one covalent bond. The noble gases in Group 0 do not form any.