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Heat energy changes in chemical reactions - EdexcelChemical bonds

Exothermic reactions in solution give out energy and the temperature increases, while endothermic reactions take in energy and the temperature decreases. Bonds are broken and made in reactions.

Part of Chemistry (Single Science)Rates of reaction and energy changes

Chemical bonds

Breaking and making bonds

is transferred when are broken or are formed.

Breaking bondsForming bonds
Type of processEndothermicExothermic
Heat energy transferredTaken inGiven out
Type of process
Breaking bondsEndothermic
Forming bondsExothermic
Heat energy transferred
Breaking bondsTaken in
Forming bondsGiven out

During a chemical reaction:

  • bonds in the are broken
  • new bonds are made in the

The difference between the energy needed to break bonds, and the energy released when new bonds form, determines the type of reaction. A reaction is:

  • - if more heat energy is released in forming bonds in the products than is taken in when breaking bonds in the reactants
  • - if less heat energy is released in forming bonds in the products than is taken in when breaking bonds in the reactants

An shows these differences more clearly.

Energy level diagrams

An energy level diagram shows the energy in the reactants and products, and the difference in energy between them.

Exothermic reaction

The energy level decreases in an exothermic reaction. This is because energy is given out to the surroundings.

Graph of energy against progress of reaction. Horizontal line represents reactants energy. Drops vertically as energy released. Horizontal line at a lower level represents products' energy.
Figure caption,
A downwards arrow shows that energy is given out

Endothermic reaction

The energy level increases in an endothermic reaction. This is because energy is taken in from the surroundings.

Graph of energy against progress of reaction. A horizontal line represents the reactants' energy. It rises vertically as energy is absorbed. A horizontal line at a higher level then represents the products' energy.
Figure caption,
An upwards arrow shows that energy is taken in