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The periodic table - AQAElectronic structure

Mendeleev made an early periodic table. In the modern periodic table, elements are in order of atomic number in periods and groups. Electronic structures model how electrons are arranged in atoms.

Part of Chemistry (Single Science)Atomic structure and the periodic table

Electronic structure

An is the way in which are arranged in an .

Electrons in shells

Electrons in atoms occupy energy levels, also called electron shells, outside the . Different shells can hold different maximum numbers of electrons. The electrons in an atom occupy the lowest available energy level first. This is the shell nearest the nucleus. When this shell is full the electrons begin to occupy the next energy level.

Below is a table showing the maximum number of electrons an element can have for each of its energy level shells. The information shown is for elements with 1 to 20:

ShellMaximum
First2
Second8
Third8
ShellFirst
Maximum2
ShellSecond
Maximum8
ShellThird
Maximum8

Predicting an electronic structure

The electronic structure of an atom can be predicted from its atomic number. For example, the atomic number of sodium is 11. Sodium atoms have 11 and so 11 electrons:

  • two electrons occupy the first shell
  • eight electrons occupy the second shell
  • one electron occupies the third shell

This electronic structure can be written as 2,8,1 (each comma, or dot, separates one shell from the next). This electronic structure can also be shown as a diagram. In these diagrams:

  • each shell is shown as a circle
  • each electron is shown as a dot or a cross
Structure of a sodium atom
Figure caption,
The electronic structure of sodium as a diagram

Electronic structures and the periodic table

The electronic structure of an is linked to its position on the .

Electronic structure featureLink to the periodic table
Number of shellsPeriod number
Number of electrons in outermost shellGroup number
Total number of electrons in all shellsAtomic number
Electronic structure featureNumber of shells
Link to the periodic tablePeriod number
Electronic structure featureNumber of electrons in outermost shell
Link to the periodic tableGroup number
Electronic structure featureTotal number of electrons in all shells
Link to the periodic tableAtomic number

The electronic structure of sodium (2,8,1) shows that sodium, Na:

  • is in period 3
  • is in group 1
  • has an atomic number of (2 + 8 + 1) = 11