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Distillation

Learn more on distillation and chromatography in this podcast.

Simple distillation

is used to separate a from a . It is useful for producing pure water from seawater.

Simple distillation works because the has a much higher than the solvent. When the solution is heated, solvent leaves the solution. It moves away and is cooled and . The remaining solution becomes more concentrated as the amount of solvent in it decreases.

Image gallerySkip image gallerySlide 1 of 3, Salty water is heated., Simple distillation 1. Salty water is heated

Fractional distillation

is used to separate different liquids from a mixture of liquids. It is useful for separating from a mixture of ethanol and water, and for separating different from crude oil.

Fractional distillation works because the different liquids have different boiling points. When the mixture is heated:

  • vapours rise through a column which is hot at the bottom, and cooler at the top
  • vapours condense when they reach a part of the column that is below the temperature of their boiling point
  • each liquid is led away from the column

There are two ways of obtaining different liquids from the column:

  • by collecting different liquids from different parts of the column - the substance with the lowest boiling point is collected at the top of the column
  • by continuing to heat the mixture to increase the temperatures in the column - the substance with the lowest boiling point is collected first
Image gallerySkip image gallerySlide 1 of 3, In the first stage of ethanol distillation, water and ethanol solution is heated., Distillation process to separate ethanol from water 1. Water and ethanol solution is heated