Extracting iron and copper
Ores
unreactiveA substance is unreactive or inert if it does not easily take part in chemical reactions.metalShiny element that is a good conductor of electricity and heat, and which forms basic oxides. such as gold are found in the Earth's crustThe outer layer of the Earth on top of the mantle. as the uncombined elementA substance made of one type of atom only.. However, most metals are found combined with other elements to form compoundA substance formed by the chemical union of two or more elements..
Most metals are extracted from oreA rock containing enough quantities of a mineral for extraction to be possible. found in the Earth's crust. An ore is a rock that contains enough of a metal or a metal compound to make extracting the metal worthwhile.
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Extraction methods
The extractionThe process of obtaining a metal from a mineral, usually by reduction or electrolysis. method used depends upon the metal's position in the reactivity seriesA list of elements in order of their reactivity, usually from most reactive to least reactive.. In principle, any metal could be extracted from its compounds using electrolysisThe decomposition (breakdown) of a compound using an electric current.. However, large amounts of electrical energyEnergy transferred by electricity. are needed to do this, so electrolysis is expensive.
If a metal is less reactiveThe tendency of a substance to undergo a chemical reaction. than carbon, it can be extracted from its compounds by heating with carbon. Copper is an example of this. Copper mostly occurs as sulfide ores, which are heated in air to convert them to copper(II) oxide. moltenA term used to describe a liquid substance (eg rock, glass or metal) formed by heating a solid. copper can be produced from copper oxide by heating with carbon:
Copper oxide + carbon 鈫 copper + carbon dioxide
2CuO(s) + C(s) 鈫 2Cu(l) + CO2(g)
Copper oxide is reductionThe loss of oxygen, gain of electrons, or gain of hydrogen by a substance during a chemical reaction. as carbon is oxidationThe gain of oxygen, or loss of electrons, by a substance during a chemical reaction., so this is an example of a redox reactionWhen reduction and oxidation take place at the same time. reaction.
The table summarises the extraction methods used for different metals.
Although an unreactive metal is found as the metal itself, chemical reactions are often needed to remove other elements that might contaminate it.
Extracting iron
Iron(III) oxide is reduced to molten iron when it reacts with carbon. One of the products is carbon monoxide:
iron(III) oxide + carbon 鈫 iron + carbon monoxide
Fe2O3(s) + 3C(s) 鈫 2Fe(l) + 3CO(g)
This method of extraction works because carbon is more reactive than iron, so it can displaceTake the place of another substance in a chemical reaction. For example, a metal can displace a less reactive metal from its oxide, removing oxide ions from the less reactive metal and becoming an oxide itself. iron from iron compounds. Extracting a metal by heating with carbon is cheaper than using electrolysis.
Question
In the reaction of iron(III) oxide with carbon, state which substance is reduced and which substance is oxidised.
Carbon gains oxygen, so it is oxidised. Iron(III) oxide loses oxygen, so it is reduced.