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Fuels - EdexcelHydrogen versus petrol

Crude oil is a finite resource. Petrol and other fuels are produced from it using fractional distillation and cracking. Combustion products may cause environmental and health problems.

Part of Chemistry (Single Science)Fuels and Earth science

Hydrogen versus petrol

For more than a century most cars have been fuelled by petrol or diesel. Hydrogen is another that can be used for cars. It has advantages over petrol but it has disadvantages too.

Production of hydrogen and petrol

Petrol

Petrol is a . It is made from , a . Some of the substances found in petrol are made by crude oil fractions, a process which uses large amounts of .

Hydrogen

Hydrogen is manufactured in several ways. These include:

  • reaction of methane from natural gas with steam
  • cracking of crude oil fractions (hydrogen is a by-product of this process)
  • of water

Methane is a non-renewable fossil fuel made from natural gas, a finite resource. The production of hydrogen from natural gas or from crude oil offers no advantage over petrol.

Question

The electrolysis of water needs large amounts of electrical energy. Explain an advantage and a disadvantage of producing hydrogen by the electrolysis of water.

Combustion products

Petrol

happens in cars fuelled with petrol. This produces:

  • carbon particles, which appear as smoke and
  • , a toxic gas

Question

Carbon dioxide is produced during the combustion of petrol. Describe a problem this causes to the environment.

Hydrogen

Hydrogen usually provides the fuel for hydrogen-oxygen in cars. However, it can also be used in some internal combustion engines (the type of engines found in petrol cars). However, water is the only product of combustion when hydrogen is used.

There are far fewer hydrogen filling stations than petrol filling stations. Depending on where you live, this could make it more difficult to run a car fuelled by hydrogen.

Filling a car at a filling station
Image caption,
Filling a car at a filling station

Other features

The table shows some other features of hydrogen and petrol as fuel for cars.

HydrogenPetrol
Ease of ignitionVery flammable - ignites easilyVery flammable - ignites easily
Energy released per kg of fuel (MJ)14246
State at room temperature and pressureGasLiquid
Ease of ignition
HydrogenVery flammable - ignites easily
PetrolVery flammable - ignites easily
Energy released per kg of fuel (MJ)
Hydrogen142
Petrol46
State at room temperature and pressure
HydrogenGas
PetrolLiquid

Question

Suggest an explanation for why hydrogen is usually liquefied by cooling or stored as a gas under pressure.