大象传媒

The ionic lattice

An is a giant structure of ions. The ions have a regular, repeating arrangement called an .

An ionic lattice is held together by strong of attraction between the oppositely charged ions. The forces act in all directions in the lattice. This is called .

Representing ionic compounds

Different types of model are used to represent giant ionic structures.

Sodium and chloride ions tightly packed in rows and columns.
Figure caption,
A two-dimensional space-filling model for the ionic lattice in sodium chloride
A three-dimensional space-filling model for the ionic lattice in sodium chloride
Figure caption,
A three-dimensional space-filling model for the ionic lattice in sodium chloride
Ionic structure of sodium chloride forming a cubic lattice
Figure caption,
A three-dimensional ball-and-stick model for the ionic lattice in sodium chloride

Remember that the lattice arrangement is giant - for example, a single grain of salt may contain 1.2 脳 1018 (1,200,000,000,000,000,000) ions. The lattice arrangement continues in three dimensions. This is why solid ionic compounds form crystals with regular shapes.

Each has its advantages and limitations. For example:

  • the two-dimensional space-filling model clearly shows the arrangement of ions in one layer, but it does not show how the next layer of ions is arranged
  • the three-dimensional ball-and-stick model shows the arrangement of ions in a larger section of the crystal, but using sticks for bonds is misleading because the forces of attraction between ions actually act in all directions
  • the three-dimensional model is also misleading because it shows lots of free space between the ions, which there isn't

Question

Use the three-dimensional ball-and-stick model to show that the formula of sodium chloride is NaCl.