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Giant covalent substances - EdexcelVery large molecules

Giant covalent substances contain atoms joined together by bonds. Diamond, graphite and graphene are forms of carbon and have different properties because they have different structures.

Part of Chemistry (Single Science)Key concepts in chemistry

Very large molecules

Graphene

is another form of carbon. Its structure resembles a single layer of . Graphene has a very high and is very strong because of its large regular arrangement of carbon joined by . Like graphite it electricity well because it has that are free to move across its surface.

Fullerenes

A is a form of the carbon. Two examples of fullerenes are and .

Nanotubes

A nanotube resembles a layer of graphene, rolled into a tube shape. Nanotubes have high , so they are strong in and resist being stretched. Like graphene, nanotubes are strong and conduct electricity because they have delocalised electrons.

Covalent structure of a nanotube
Figure caption,
Nanotubes can be several millimetres long but only a few nanometres wide

Buckyballs

Buckyballs are spheres or squashed spheres of carbon atoms. They are made up of large molecules so are not classed as giant . Weak exist between buckyballs. These need little to overcome, so substances consisting of buckyballs are slippery and have lower than graphite or .

Covalent structure of buckminsterfullerene
Figure caption,
Buckminsterfullerene has sixty carbon atoms joined by covalent bonds

Polymers

Simple consist of large that contain chains of carbon atoms of no set size.

A model of a short section of a poly(ethene) molecule, a simple polymer. Polythene molecules will contain thousands of carbon atoms joined together in a chain
Figure caption,
A model of a short section of a poly(ethene) molecule, a simple polymer. Polythene molecules will contain thousands of carbon atoms joined together in a chain.