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Atomic structure - EdexcelAtomic number and mass number

Atoms consist of a nucleus containing protons and neutrons, surrounded by electrons in shells. The numbers of particles in an atom can be calculated from its atomic number and mass number.

Part of Chemistry (Single Science)Key concepts in chemistry

Atomic number and mass number

Atomic number

The of an is the number of in its . Remember that:

  • all the atoms of a given have the same atomic number
  • the atomic number of each element is unique - no two elements have the same atomic number

An atom contains equal numbers of protons and . Since protons and electrons have equal and opposite , this means that atoms are overall.

For example, the atomic number of chlorine is 17. Every chlorine atom has 17 protons and 17 electrons. It has 17 positive charges and 17 negative charges, meaning that it is neutral overall.

Mass number

Atoms of different elements usually have different mass numbers, but they can be the same. For example, the mass number of argon atoms and calcium atoms can both be 40.

Calculating numbers of subatomic particles

The symbol for an atom can be written to show its mass number at the top, and its atomic number at the bottom.

Chlorine 35 square from the periodic table. The mass number (35) is top-left. The atomic number (17) is bottom-left.

To calculate the numbers of in an atom use its atomic number and mass number:

  • number of protons = atomic number
  • number of electrons = atomic number
  • number of neutrons = mass number - atomic number

An interactive lesson in calculating an atom's mass and atomic number

Question

The atomic number of a chlorine atom is 17 and its mass number is 35. Calculate the number of protons, neutrons and electrons it contains.