Polymer problems
One of the useful propertiesThe characteristics of something. In chemistry, chemical properties include the reactions a substance can take part in. Physical properties include colour and boiling point. of polymerA large molecule formed from many identical smaller molecules known as monomers. is that they are unreactiveA substance is unreactive or inert if it does not easily take part in chemical reactions.. This means they are suitable for storing food and other substances safely. Unfortunately, this property makes it difficult to dispose of polymers.
Not biodegradable
Most polymers, including poly(ethene) and poly(propene) are not biodegradableMaterial that can be broken down in the environment by microorganisms.. This means that micro organismsMicroscopic living things such as archaea, bacteria and some species of eukaryotes. cannot break them down, so they:
- cause a litter problem if disposed of carelessly
- last for many years in landfill sitesPlaces where refuse is buried underground.
Suitable places for landfill sites are difficult to find. Space in landfill sites is wasted if it is filled with non-biodegradable polymers.
Question
Describe what 'biodegradable' means.
If something is biodegradable, it can be broken down or decomposed by microorganisms.
Combustion
Waste polymers can be incineratedBurned, particularly at a high heat.. This involves combustionThe process of burning by heat. at very high temperatures. Incineration releases a lot of energyThe capacity of a system to do work or the quantity required for mechanical work to take place. Measured in joules (J). For example, a man transfers 100 J of energy when moving a wheelbarrow. which can be used to heat homes or to generate electricity.
There are problems with incineration:
- carbon dioxide is produced, a greenhouse gasThe gases responsible for global warming - carbon dioxide, methane, nitrous oxide and CFCs (chlorofluorocarbons). which contributes to global warmingThe rise in the average temperature of the Earth's surface.
- toxicPoisonous. gases are produced which need removing before they leave the chimney
Recycling
The use of landfill and incineration wastes valuable resourceAnything that is useful to people. . crude oilMixture of hydrocarbons, mainly alkanes, formed over millions of years from the remains of ancient dead marine organisms. is the raw material for making most polymers, and it is a finite resourceA resource that is no longer being made or which is made extremely slowly, such as crude oil and metal ores.. recyclingReusing materials or reprocessing waste materials to produce new materials. reduces the problems of disposal, and also reduces the volume of crude oil used.
Recycling involves:
- melting the waste polymer
- forming the polymer into a new product
However, different polymers must be separated from each other first. This can be difficult and expensive to do.