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Using equations to represent chemical reactionsWorking out the charges of ions

All substances are described by their formulae, which are used to write balanced chemical equations. Writing the formula for an ionic compound requires knowledge of the charges on its ions.

Part of Chemistry (Single Science)Chemical patterns

Working out the charges of ions

The of many can be worked out using patterns in the . in the same form ions with the same charge.

The charge of many ions can be worked out from using patterns in the Periodic Table.

(in the central block between groups 2 and 3) can have ions with different charges. The number in the name of the shows the charge of the metal ions in that compound.

For example, copper(II) sulfate contains Cu2+ ions.

The table shows the of some common transition metal ions.

Metal ionFormula
Silver(I)Ag+
Copper(II)Cu2+
Lead(II)Pb2+
Iron(II)Fe2+
Iron(III)Fe3+
Metal ionSilver(I)
FormulaAg+
Metal ionCopper(II)
FormulaCu2+
Metal ionLead(II)
FormulaPb2+
Metal ionIron(II)
FormulaFe2+
Metal ionIron(III)
FormulaFe3+

are formed from groups of . The table shows the names and formulae of some of these ions.

Cations (positively charged)Anions (negatively charged)
Ammonium NH4+Hydroxide OH-
Nitrate NO3-
Carbonate CO32-
Sulfate SO42-
Cations (positively charged)Ammonium NH4+
Anions (negatively charged)Hydroxide OH-
Cations (positively charged)
Anions (negatively charged)Nitrate NO3-
Cations (positively charged)
Anions (negatively charged)Carbonate CO32-
Cations (positively charged)
Anions (negatively charged)Sulfate SO42-

The formulae of compounds containing polyatomic ions are worked out in a similar way to single atom ions. If more than one polyatomic ion is needed, its formula is written inside brackets.

Example

Calcium hydroxide contains Ca2+ and OH- ions:

  • this is two positive charges and one negative charge
  • to balance it will need, one Ca2+ ion and two OH- ions,
  • so its formula is Ca(OH)2

Question

Deduce the formula for sodium carbonate.

Question

Deduce the formula for lead(II) nitrate.

Naming ionic compounds with -ide and -ate

The name of an ends in:

  • -ide if it contains just two elements
  • -ate if it contains three or more elements, one of which is oxygen
Name (-ide)FormulaName (-ate)Formula
Calcium carbideCaC2Calcium carbonateCaCO3
Potassium iodideKIPotassium iodateKIO3
Iron(II) sulfideFeSIron(II) sulfateFeSO4
Name (-ide)Calcium carbide
FormulaCaC2
Name (-ate)Calcium carbonate
FormulaCaCO3
Name (-ide)Potassium iodide
FormulaKI
Name (-ate)Potassium iodate
FormulaKIO3
Name (-ide)Iron(II) sulfide
FormulaFeS
Name (-ate)Iron(II) sulfate
FormulaFeSO4