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If we're talking anti-valentine, rather than sad, I feel bad, breakup songs, I have to go with stuff like I Will Survive and Hit the road Jack. Stuff that says I don't need you anymore anyway, rather than I can't go on now you've left.

Paul Simon's "50 Ways To Leave Your Lover" is an obvious choice.

Ben Folds Five - Song for the Dumped (Ben Folds is a bit of a potty mouth in this song though - you have been warned!)

Alanis Morrisette's "You Outta Know" - chock-full of resentment and bitterness throughout. Marvellous anti-Valentine stuff.

Elton John's If It Wasn’t For Bad comes to mind.

Nancy Sinatra - These Boots Are Made for Walkin'

Not a breaking-up song, but a brilliant tale of a relationship where the love is long since gone - The Mountain Goats' No Children

'My girlfriend's dead' by the Vandals. Always makes me giggle.

Long Enough To Forget You - Samiam
Song For The Dumped - Ben Folds Five (a bit sweary)
No Hard Feelings - Bloodhound Gang (completely obscene)

Cee Lo Green's 'Forget You'?
(although another f word in the rude version gives the song more ooomph)

How Could You Believe Me When I Said I Loved You When You Know I've Been A Liar All My Life

Jilted John by Jilted John is a perfect anti-valentines song.

I second Cee Lo Green's (uncensored version of) 'Forget You', and my personal favourite, Gives You Hell by the All American Rejects. Oh, I've screeched that one a few times...

How about "You're so Vain" by Carly Simon.
The line "I bet you think this song is about you" is just delicious!!!

Adele: Rolling In The Deep

Ironically, REM's 'The One I Love' - scourge of weddings worldwide and melodiously, odiously regarding "A simple prop, to occupy my time". Fire.

NOFX - Happy break up song
Vandals - My girlfriends dead
Type o negative - Unsuccesfully coping with the natural beauty of infedelity (give that one a try, it may not seem it from the title but it does have a good oomph to it)

Heaven knows im miserable now by the smiths.

Dance the night away by the Mavericks

"I Want You To Die" by the sexually omnivorous Portland chanteuse Storm Large says it all.

How about "She" by Green Day?

"Everybody Loves Me But You"-Peggy Lee amongst others.

There's always the lazy DJ's favourite, Godley & Cream's "Wedding Bells". Heard a radio 1 dj play it in the late 80's. The stunned silence @ the end was great

Two suggestions:

She Hates Me by Puddle of Mudd. Sweary version is my favourite, for the sheer venom.

Haha You're Dead by Green Day. Always makes me smile.

My two favourites in the old non-Valentine category: 'Shut Up and Drive' by Chely Wright (for when you're still at that 'did I do the right thing' stage and need some support from your inner self) and 'I Need a Little Time' by The Beautiful South (for all those who've ever been treated badly by someone who thought they could walk back in and pout a little and say the 'L' word and everything would be okay) In the final verse 'You had a little time and you had a little fun, didn't you? Didn't you? While you had yours do you think I had none? Do ya?' is just perfect.

Also, I hate everything about you by Ugly Kid Joe.

If the radio is on on a Sunday morning, Steve Wright devotes an entire program to Love Songs on ´óÏó´«Ã½ Radio 2...although I'm frequently in fits at the inappropriate choices.
George Michael's "Careless Whisper" (about him being caught cheating) and Witney's "I will always love you" (her wailing about having been dumped) are particular howlers.
However, yesterday surpassed all expectations with Johnny Mathis and Denise Williams belting out "Too much, too little, too late". Inspired!

Not quite breaking up, but definitely doomed relationships:

- "Self Esteem" by The Offspring (explicit)
- "Ballad of an Upstairs Window" by Pete Atkin

I can't believe noone's gone for the obvious (surely?): Tammy Wynette, DIVORCE

or Martha Wainwright's 'You cheated me' (from 'I know you're married but I've got feelings too')

"You're the Reason Our Kids Are Ugly" (Loretta Lynn). It's the only Country & Western song I can stand.

I had a friend who went to a family wedding at which the happy couple had their first dance to 'Band of Gold' by Freda Payne, much to the bemusement of my friend and probably most of the other guests!

As for anti-Valentines, Guns n' Roses' 'Used To Love Her' is fairly...evocative!

I went to a wedding where the couple's first dance was to Lionel Richie's 'Easy Like Sunday Morning'. If you're not paying attention, it sounds like a lovely song. But the opening line? "I know it sounds funny but I just can't stand the pain; Girl I'm leaving you tomorrow..." They are divorced now.

Happy to be free:
- Since U Been Gone by Kelly Clarkson
- You'll Think Of Me by Keith Urban

Wishing it was different:
- Single Girl - Lush
- Ex-Girlfriend - No Doubt

And then there's the dialogue in Ciao! by Lush...

Tom Lehrer's "When you are old and grey".

"Bust Your Windows" by Jazmine Sullivan:
I bust the windows out your car
And no it didn't mend my broken heart
I'll probably always have these ugly scars
But right now, I don't care about that part

Trick me Once by Kelis is a particular favourite, as is How to say Goodbye by the Magnetic Fields.

Early Limp Bizkit before they sucked when Fred Durst was a very angry man, and clearly directing his rage at a certain relationship:

3 $Dollar Bills Y'all ~ Stuck.
If just for the repeated yelling at the end.

Also Nookie is good contender.
All the early stuff is fully Anti Valentine, which got him labeled a misognist.

Pantera ~ This Love

And even though I don't like this song:

All American Rejects - Gives you Hell

A bit poppy, but 'Please Mr Postman' (Beatles/Carpenters) and 'Return to Sender' (Elvis) are two which make me want to shout "Give up - she doesn't want you!!"

Surely Carole Bayer Sagar's "You're Moving Out Today" is the ultimate antiValentine's song. Angry, but clear that the right thing is being done!

Dead from the Waist Down by Catatonia

Another great one from Martha Wainwright, although probably to obscene to even post the full title on here..... B..M..F..A...

Heart-Shaped box, Nirvana, suitably dark

'Puke', off the Encore album, by Eminem.

'Good Riddance' by Green Day is another one.

A few that spring to mind:

Guns N Roses - Back Off B**ch

Damon - I Don't Want you back (for the boys)

Frankee - F.U.R.B. (for the girls)

Rhianna - Take A Bow

Beyonce - Single Ladies

Cameo - Single Life

....and I will probably get all manner of comments about my taste in music (and before anyone asks, I am very much in love with a beautiful young lady, no apologies for being slushy and loved up).

The Bluetones - Never Going Nowhere: Some words will cut you, like the sharpest knife. I don't love you anymore, I don't love you anymore.

All to a very upbeat and hummable tune.

Madeleine Peyroux - You'll make me lonesome when you're gone

"I used to love her, but I had to kill her" - Richard Cheese (quite possibly a cover, but Richard Cheese is great)

Everyday I Love You Less And Less by the Kaiser Chiefs

'Ain't No Sunshine' - Bill Withers come on man classic!

McCartney...."I've had enough, can't put up with anymore"

How about Alkalne Trio's 'Another Innocent Girl' great tune, full of a bit of angst or the Offsprings 'Feelings'.....

How about Kelis "Out There" - especially love the bit where she screams "I hate you so much right now! AAAARGH!" or Cockney Rebel "Smile"

"where do you go to my lovely" - Peter Sarstedt

The Pebbles series of records has some great examples. "Go Away" by the Plague opens with: "Go away! 'cause I hate you! Go away! I won't date you! Get away from my door!", all to an ersatz Kinks soundtrack. Wonderful!

One More Minute by "Weird Al" Yankovic

"I'll rather clean all the bathroom in Grand Central Station with my tongue, then spend, one more minute, with you"

Nobody Loves a Fairy When She's Forty! - one for the missus.

Guns 'n' Roses - I Used to Love Her (but I had to kill her)

Green Day - Whatsername

"I Love You Because (You Look Like Jim Reeves)" -half-man half-biscuit....