大象传媒

Ionic compounds - EdexcelForming ions

When a metal element reacts with a non-metal element an ionic compound is formed. They have a giant lattice structure with strong ionic bonds. A lot of energy is needed to overcome these bonds.

Part of Combined ScienceKey concepts in chemistry

Forming ions

An is an or group of atoms with a positive or negative . Ions form when atoms lose or gain to obtain a full outer shell:

  • atoms lose electrons to form positively charged ions
  • atoms gain electrons to form negatively charged ions

Learn more on ionic bonding in this podcast.

Forming positive ions

Metal atoms lose electrons from their outer shell when they form ions:

  • the ions formed are positive, with more than electrons
  • the ions formed have full outer shells

For elements in 1, 2 and 3, the number of electrons lost is the same as the group number.

How a sodium atom becomes a sodium ion when it loses an electron
Figure caption,
A sodium atom loses one electron to form a sodium ion

Forming negative ions

The outer shell of non-metal atoms gains electrons when they form ions:

  • the ions formed are negative, because they have more electrons than protons
  • the ions formed have full outer shells

For groups 6 and 7, the number of electrons gained is equal to (8 - group number).

How an oxygen atom becomes an oxygen ion when it gains two electrons
Figure caption,
An oxygen atom gains two electrons to form an oxide ion

Example of ion charges and groups

Group numberElementCharge on ionsSymbol of ion
1Na+Na+
2Mg2+Mg2+
3Al3+Al3+
6O2-O2-
7Cl-Cl-
Group number1
ElementNa
Charge on ions+
Symbol of ionNa+
Group number2
ElementMg
Charge on ions2+
Symbol of ionMg2+
Group number3
ElementAl
Charge on ions3+
Symbol of ionAl3+
Group number6
ElementO
Charge on ions2-
Symbol of ionO2-
Group number7
ElementCl
Charge on ions-
Symbol of ionCl-

The numbers of protons, and electrons in an ion can be calculated from its , and ionic charge.

Remember that:

  • atomic number = protons
  • mass number = protons + neutrons
  • electrons = protons (if atom is neutral)
  • positive ions have lost electrons
  • negative ions have gained electrons

Some examples are shown in the table below:

Ion nameIon symbolAtomic numberMass numberProtonsNeutronsElectrons
AluminiumAl3+1327131410
CalciumCa2+2040202018
SulfideS2-1632161618
Ion nameAluminium
Ion symbolAl3+
Atomic number13
Mass number27
Protons13
Neutrons14
Electrons10
Ion nameCalcium
Ion symbolCa2+
Atomic number20
Mass number40
Protons20
Neutrons20
Electrons18
Ion nameSulfide
Ion symbolS2-
Atomic number16
Mass number32
Protons16
Neutrons16
Electrons18