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Giant covalent substances - EdexcelSubstances with many covalent bonds

Giant covalent substances contain atoms joined together covalent by bonds. Diamond, graphite and graphene are forms of carbon and have different properties because they have different structures.

Part of Combined ScienceKey concepts in chemistry

Substances with many covalent bonds

leads to the formation of . These can be:

  • simple molecules, which contain a set number of joined by covalent bonds
  • giant substances, which contain many atoms joined by covalent bonds

Learn more on properties of giant covalent compounds in this podcast.

An example - silica

Silica is the main found in sand. It is an example of a giant covalent substance. It contains many silicon and oxygen atoms. These are joined together by covalent bonds in a regular arrangement, forming a giant or structure. There is no set number of atoms joined together in this type of structure, so these covalent lattices are not classed as molecules. However, the atoms in the compound will be present in the ratio indicated by the chemical .

A ball and stick model of silica
Figure caption,
Silica has a giant covalent structure containing silicon atoms (grey) and oxygen atoms (red)

High melting points and boiling points

Giant covalent substances are solids at room temperature and have very high and . Covalent bonds are strong, so a lot of is needed to break up these large structures during melting and boiling.

Conduction of electricity

Giant covalent substances have no overall , so most cannot electricity. Graphite, a form of carbon, which can conduct electricity, is an exception.

Insoluble in water

A substance can in water if it forms strong enough attractions with water molecules. Giant covalent substances cannot form these strong attractions with water, so they are .