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Finding the composition of unknown samplesFlame tests

Quantitative analysis is used by chemists to make measurements and calculations. Alkalis neutralise acids to make salts and water. Their concentration can be analysed using titrations.

Part of Chemistry (Single Science)Chemical analysis

Flame tests

There are several different tests to detect and identify the in . It is important that the test for any ion is unique and that the results of a test determine accurately which ion is present, rather than being uncertain about which ion it is.

Flame tests

Different ions produce different flame colours when they are heated strongly. This is the basis of flame tests. The steps of a flame test are:

  1. dip wire loop in hydrochloric acid to clean
  2. check that the wire loop is clean by holding in flame - if no colour is seen, the loop is clean
  3. dip a clean wire loop into a solid sample of the compound being tested
  4. put the loop into the edge of the blue flame from a Bunsen burner
  5. observe and record the flame colour produced
A sample is held in a Bunsen burner flame and burns red.
Figure caption,
Carrying out a flame test

The table shows the flame test colours for five common metal ions.

Ion presentFlame test colour
Lithium, Li+Bright red
Sodium, Na+Bright yellow
Potassium, K+Lilac
Calcium, Ca2+Orange-red
Copper, Cu2+Blue-green
Ion presentLithium, Li+
Flame test colourBright red
Ion presentSodium, Na+
Flame test colourBright yellow
Ion presentPotassium, K+
Flame test colourLilac
Ion presentCalcium, Ca2+
Flame test colourOrange-red
Ion presentCopper, Cu2+
Flame test colourBlue-green

Question

A sample of an produces an orange-red flame test colour. Identify the metal ion present.