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Atomic structure - EdexcelIsotopes

Atoms consist of a nucleus containing protons and neutrons, surrounded by electrons in shells. The numbers of particles in an atom can be calculated from its atomic number and mass number.

Part of Combined ScienceKey concepts in chemistry

Isotopes

of an that have the same number of , but different numbers of in their are called . Isotopes of an element have:

  • the same
  • different

Three isotopes of hydrogen

All hydrogen atoms contain one proton (and one ), but they can contain different numbers of neutrons. Hydrogen-1 is the most isotope of hydrogen.

IsotopeSymbolProtonsNeutronsElectrons
Hydrogen-1\(_{1}^{1}\textrm{H}\)11 - 1 = 01
Hydrogen-2\(_{1}^{2}\textrm{H}\)12 - 1 = 11
Hydrogen-3\(_{1}^{3}\textrm{H}\)13 - 1 = 21
IsotopeHydrogen-1
Symbol\(_{1}^{1}\textrm{H}\)
Protons1
Neutrons1 - 1 = 0
Electrons1
IsotopeHydrogen-2
Symbol\(_{1}^{2}\textrm{H}\)
Protons1
Neutrons2 - 1 = 1
Electrons1
IsotopeHydrogen-3
Symbol\(_{1}^{3}\textrm{H}\)
Protons1
Neutrons3 - 1 = 2
Electrons1

An isotope is named after the element and the mass number of its atoms. For example, carbon-12 is an isotope of carbon with a mass number of 12.

All three isotopes of hydrogen have identical chemical . This is because the number of electrons determines chemical properties, and all three isotopes have one electron in their atoms.

Learn more on isotopes in this podcast.

Relative atomic mass

are given in the periodic table. They have the symbol Ar.

Take care not to confuse mass numbers and relative atomic masses:

  • mass numbers are always whole numbers (it is not possible to have part of a proton or neutron)
  • relative atomic masses are often rounded to the nearest whole number, but are actually not whole numbers

For example, the relative atomic mass of chlorine is 35.5 rather than a whole number. This is because chlorine contains two different isotopes, chlorine-35 and chlorine-37.